GCEChemistryAcids, Bases and Salts2021

A buffer solution is prepared by mixing 0.20 mol of ethanoic acid with 0.20 mol of sodium ethanoate in 1 dm³ of solution. Given that the $\text{p}K_a$ of ethanoic acid is 4.76, what is the pH of the buffer?

A3.76
B4.76CORRECT
C5.76
D7.00
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Why the answer is B, and why the others tempt you.
Using the Henderson–Hasselbalch equation: pH = pKa + log([A⁻]/[HA]) = 4.76 + log(0.20/0.20) = 4.76 + log(1) = 4.76 + 0 = 4.76. When the concentrations of the weak acid and its conjugate base are equal, the pH equals the pKa of the acid.
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