In electrolysis of water, the gas evolved at the cathode is:
AOxygen
BHydrogenCORRECT
CChlorine
DNitrogen
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Why the answer is B, and why the others tempt you.
**The reasoning**
In electrolysis of water, we're using electricity to split H₂O molecules. Here's the key principle: **cathodes attract cations (positive ions)**.
The reaction: 2H₂O → 2H₂ + O₂
Water contains H⁺ ions (from H₂O dissociation). At the **cathode (negative electrode)**, these H⁺ ions are attracted and gain electrons:
2H⁺ + 2e⁻ → H₂ ↑
At the **anode (positive electrode)**, OH⁻ ions lose electrons:
4OH⁻ → O₂ + 2H₂O + 4e⁻
So **hydrogen gas bubbles at the cathode**, oxygen at the anode.
**Why the wrong options tempt you**
**A) Oxygen** — This is the biggest trap! Oxygen *is* produced, but at the anode (positive electrode), not the cathode. Students mix up which gas goes where.
**C) Chlorine & D) Nitrogen** — These aren't even in water's formula (H₂O), so they can't form.
**Quick takeaway**
Remember: **"Cats are positive"** — **Cat**hodes attract **positive** H⁺ ions, producing hydrogen gas. The anode gets oxygen because it attracts negative OH⁻ ions.
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